K (Lat kalium), element 19, melting point 63°C. One of the most reactive metals, and the third of the alkali metal group. It is not found free in nature, but obtained chiefly from mineral deposits of the chloride (KCl) and the nitrate (KNO3, also known as nitre or saltpetre). The metal is prepared by the electrolysis of molten KCl or KOH. It is an important strong reducing agent, and must be kept away from water, with which it reacts explosively. In virtually all of its compounds, it has oxidation state +1. These are important mainly as agricultural chemicals and explosives.
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| General | |||||||||||||||||||||||||||||||
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| Name, Symbol, Number | potassium, K, 19 | ||||||||||||||||||||||||||||||
| Chemical series | alkali metals | ||||||||||||||||||||||||||||||
| Group, Period, Block | 1, 4, s | ||||||||||||||||||||||||||||||
| Appearance |
brownish white |
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| Atomic mass | 39.0983(1) g/mol | ||||||||||||||||||||||||||||||
| Electron configuration | [Ar] 4s1 | ||||||||||||||||||||||||||||||
| Electrons per shell | 2, 8, 8, 1 | ||||||||||||||||||||||||||||||
| Physical properties | |||||||||||||||||||||||||||||||
| Phase | solid | ||||||||||||||||||||||||||||||
| Density (near r.t.) | 0.89 g·cm−3 | ||||||||||||||||||||||||||||||
| Liquid density at m.p. | 0.828 g·cm−3 | ||||||||||||||||||||||||||||||
| Melting point |
336.53 K (63.38 °C, 146.08 °F) |
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| Boiling point |
1032 K (759 °C, 1398 °F) |
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| Critical point | ( K, {{{mpa}}} MPa | ||||||||||||||||||||||||||||||
| Crystal structure | cubic body centered | ||||||||||||||||||||||||||||||
| Oxidation states |
1 (strongly basic oxide) |
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| Electronegativity | 0.82 (Pauling scale) | ||||||||||||||||||||||||||||||
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Ionization energies (more) |
1st: 418.8 kJ·mol−1 | ||||||||||||||||||||||||||||||
| 2nd: 3052 kJ·mol−1 | |||||||||||||||||||||||||||||||
| 3rd: 4420 kJ·mol−1 | |||||||||||||||||||||||||||||||
| Atomic radius | 220 pm | ||||||||||||||||||||||||||||||
| Atomic radius (calc.) | 243 pm | ||||||||||||||||||||||||||||||
| Covalent radius | 196 pm | ||||||||||||||||||||||||||||||
| Van der Waals radius | 275 pm | ||||||||||||||||||||||||||||||
| Miscellaneous | |||||||||||||||||||||||||||||||
| Magnetic ordering | ? | ||||||||||||||||||||||||||||||
| Thermal conductivity | (300 K) 102.5 W·m | ||||||||||||||||||||||||||||||
| Thermal expansion | (25 °C) 83.3 µm·m | ||||||||||||||||||||||||||||||
| Speed of sound (thin rod) | (20 °C) 2000 m/s | ||||||||||||||||||||||||||||||
| Shear modulus | 1.3 GPa | ||||||||||||||||||||||||||||||
| Bulk modulus | 3.1 GPa | ||||||||||||||||||||||||||||||
| Mohs hardness | 0.4 | ||||||||||||||||||||||||||||||
| Brinell hardness | 0.363 MPa | ||||||||||||||||||||||||||||||
| CAS registry number | 7440-09-7 | ||||||||||||||||||||||||||||||
| Selected isotopes | |||||||||||||||||||||||||||||||
Main article: Isotopes of potassium
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| References | |||||||||||||||||||||||||||||||
Potassium (IPA: /pə(ʊ)ˈtasiəm/) is a chemical element. In animal cells potassium ions are vital to keeping cells alive (see Na-K pump) Potassium chloride is used as a substitute for table salt and is also used to stop the heart, e.g.
Many potassium salts are very important, and include: potassium bromide, potassium carbonate, potassium chlorate, potassium chloride, potassium chromate, potassium cyanide, potassium dichromate, potassium iodide, potassium nitrate, potassium sulfate.
See also potassium minerals.
Isotopes
There are seventeen known isotopes of potassium.
Potassium in nutrition and medicine
Potassium is an essential mineral micronutrient in human nutrition;
Supplements of potassium in medicine are most widely used in conjunction with the most powerful classes of diuretics, which rid the body of sodium and water, but have the side effect of also causing potassium loss in urine. End stage renal failure patients undergoing therapy by renal dialysis must observe strict dietary limits on potassium intake, since the kidneys control potassium excretion, and buildup of blood concentrations of potassium may trigger fatal heart dysrhythmias.
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