Cambridge Encyclopedia :: Cambridge Encyclopedia Vol. 61

pyrite - Pyrite and marcasite, Formal oxidation states for pyrite, marcasite, and arsenopyrite

A metallic yellow iron sulphide (FeS2) mineral, common and widespread, often occurring as well-formed cubic crystals; also termed ‘fool's gold’ because of its colour. It is used as a source of sulphur and in the manufacture of sulphuric acid.

Pyrite

A mass of intergrown, striated pyrite crystals

Euhedral cubic pyrite crystals

General
Category Mineral
Chemical formula iron disulfide (FeS2)
Identification
Colour Pale, dull gold
Crystal habit Cubic, faces may be striated, but also frequently octahedral and pyritohedron.
Crystal system Isometric; bar 3 2/m
Melting Point 1,177-1,188°C
Cleavage Poor
Fracture Very uneven, sometimes conchoidal
Mohs Scale hardness 6 - 6.5
Luster Metallic, glistening
Refractive index Opaque
Streak Greenish-black to brownish-black
Specific gravity 4.95 - 5.10
Fusibility 2.5-3
Solubility insoluble in water
Magnetism paramagnetic

The mineral pyrite, or iron pyrite, is iron sulfide, FeS2.

Pyrite exposed to the environment during mining and excavation reacts with oxygen and water to form sulfuric acid, resulting in acid mine drainage.

Pyrite and marcasite

Pyrite is often confused with the mineral marcasite, a name derived from the Arabic word for pyrite, due to their similar characteristics. Marcasite is a polymorph of pyrite, which means it has the same formula as pyrite but a different structure and, therefore, different symmetry and crystal shapes.

Marcasite is metastable relative to pyrite and will slowly be changed to pyrite if heated or given enough time.

Formal oxidation states for pyrite, marcasite, and arsenopyrite

From the perspective of classical inorganic chemistry, which assigns formal oxidation states to each atom, pyrite is probably best described as Fe.

Related minerals and varieties

Bravoite is a nickeloan variety of pyrite, with >50% substitution of Ni within pyrite.

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