Cambridge Encyclopedia :: Cambridge Encyclopedia Vol. 68

silver

Ag (Lat argentum), element 47, melting point 961°C. A lustrous transition metal, relatively rare, but occurring uncombined in nature, known and used since ancient times. It also occurs as a sulphide (Ag2S), particularly along with those of other elements; a major source is the sludge from copper refinement. Of all elements, it is the best conductor of electricity. Long used extensively in coinage, it has now become too expensive for that purpose. Much used in jewellery and medals, it requires regular cleaning, as the surface becomes coated with Ag2S. Its compounds, which normally show oxidation state +1 (especially AgBr), are used in photography; surfaces of AgBr, after activation by light, are easily reduced to Ag.

47 palladium ← silver → cadmium
Cu

Ag

Au
Periodic Table - Extended Periodic Table
General
Name, Symbol, Number silver, Ag, 47
Chemical series transition metals
Group, Period, Block 11, 5, d
Appearance lustrous white metal
Atomic mass 107.8682(2) g/mol
Electron configuration [Kr] 4d
Electrons per shell 2, 8, 18, 18, 1
Physical properties
Color silver
Phase solid
Density (near r.t.) 10.49 g·cm−3
Liquid density at m.p. 9.320 g·cm−3
Melting point 1234.93 K
(961.78 °C, 1763.2 °F)
Boiling point 2435 K
(2162 °C, 3924 °F)
Heat of fusion 11.28 kJ·mol−1
Heat of vaporization 258 kJ·mol−1
Heat capacity (25 °C) 25.350 J·mol
Vapor pressure
P/Pa 1 10 100 1 k 10 k 100 k
at T/K 1283 1413 1575 1782 2055 2433
Atomic properties
Crystal structure face-centered cubic
Oxidation states 1
(amphoteric oxide)
Electronegativity 1.93 (Pauling scale)
Ionization energies 1st: 731.0 kJ/mol
2nd: 2070 kJ/mol
3rd: 3361 kJ/mol
Atomic radius 160 pm
Atomic radius (calc.) 165 pm
Covalent radius 153 pm
Van der Waals radius 172 pm
Miscellaneous
Magnetic ordering diamagnetic
Electrical resistivity (20 °C) 15.87 nΩ·m
Thermal conductivity (300 K) 429 W·m
Thermal diffusivity (300 K) 174 mm²/s
Thermal expansion (25 °C) 18.9 µm·m
Speed of sound (thin rod) (r.t.) 2680  m·s−1
Young's modulus 83 GPa
Shear modulus 30 GPa
Bulk modulus 100 GPa
Poisson ratio 0.37
Mohs hardness 2.5
Vickers hardness 251 MPa
Brinell hardness 24.5 MPa
CAS registry number 7440-22-4
Selected isotopes
Main article: Isotopes of silver
iso NA half-life DM DE (MeV) DP
105Ag syn 41.2 d ε - 105Pd
γ 0.344, 0.280,
0.644, 0.443
-
Ag syn 8.28 d ε - 106Pd
γ 0.511, 0.717,
1.045, 0.450
-
107Ag 51.839% Ag is stable with 60 neutrons
Ag syn 418 y ε - 108Pd
IT 0.109 108Ag
γ 0.433, 0.614,
0.722
-
109Ag 48.161% Ag is stable with 62 neutrons
111Ag syn 7.45 d β- 1.036, 0.694 111Cd
γ 0.342 -
References

Silver (IPA: /ˈsɪlvə/) is a chemical element with the symbol Ag (Latin: argentum). Silver sulfide, also known as Silver Whiskers, is formed when silver electrical contacts are used in an atmosphere rich in hydrogen sulfide.

Silver mining was a driving force in the settlement of western North America, with major booms for silver and associated minerals (primarily lead) in the galena ore silver is most commonly found in.

Silver and compounds containing silver (like colloidal silver) can be absorbed into the circulatory system and become deposited in various body tissues leading to a condition called argyria which results in a blue-grayish pigmentation of the skin, eyes, and mucous membranes.

Publications on health effects

Systemic argyria associated with ingestion of colloidal silver Myoclonic status epilepticus following repeated oral ingestion of colloidal silver Specific Inactivation of Herpes Simplex Virus by Silver Nitrate at Low Concentrations and Biological Activities of the Inactivated Virus Prevention of Herpes Keratoconjunctivitis in Rabbits By Silver Sulfadiazine

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