Cambridge Encyclopedia :: Cambridge Encyclopedia Vol. 18

cresol

(CH3)C6H4(OH), three isomeric compounds: 2-, 3-, and 4-hydroxytoluene, oils with boiling point c.200°C. They are ingredients of coal tar, and are important raw materials for plastics.

Isomers of Cresol
General
Common name o-cresol m-cresol p-cresol
Systematic name 2-methylphenol 3-methylphenol 4-methylphenol
Other names ortho-cresol meta-cresol para-cresol
Molecular formula C7H8O
SMILES Oc1c(C)cccc1 Oc1cc(C)ccc1 Oc1ccc(C)cc1
Molar mass 108.14 g/mol
Appearance at room
temperature and pressure
greasy-looking solid
ready to melt
on hot day
thicker liquid greasy-looking solid
CAS number [95-48-7] [108-39-4] [106-44-5]
CAS number for mixture of cresols [1319-77-3]
Properties
Density and phase 1.05 g/cm3, liquid 1.03 g/cm3, liquid 1.02 g/cm3, liquid
Solubility in pure water
at 20-25°C
2.5 g/100 ml 2.4 g/100 ml 1.9 g/100 ml
soluble in strongly alkaline water
Melting point 29.8 °C (303.0 K) 11.8 °C (285.0 K) 35.5 °C (309.7 K)
Boiling point 191.0 °C (464.2 K) 202.0 °C (475.2 K) 201.9 °C (475.1 K)
Acidity (pKa)  ?
Viscosity solid at 25 °C  ? cP at 25 °C solid at 25 °C
Structure
Molecular shape  ? D
Hazards
MSDS External MSDS  ?
Main hazards flammable, ingestion and inhalation toxicity hazard
Flash point 81°C c.c.
R/S statement R: 24/25-34 S: (1/2-)36/37/39-45
RTECS number  ?
Thermodynamic data Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Related phenols phenol, xylenols
Related compounds  ?

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